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Innovation in Nanoporous Chemistry PDF Print
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Everything Physical Science
Written by Everything Science   
Sep 30, 2005 at 11:00 PM
Science researchers from the University of Versailles (France), in collaboration with the ID31 beam line at the European Synchrotron Radiation Facility (ESRF), report their progress in the design and characterisation of microporous materials. The combination of adept chemistry and computational design made possible the synthesis of a new material, named MIL-101 by its originators, (where MIL stands for Matériaux de l’Institut Lavoisier), with very large internal pores (ø~3.4nm) and surface area (5,900 m2.g-1). The new, crystalline material is representative of a class of compounds, known as metal organic framework materials, (MOFs), with potential applications in many fields including chemical separation, heterogeneous catalysis and gas storage. Confirmation of the structure of the new material exploited the intense X-ray beams at the ESRF.

Starting from simple assemblies and linking units, larger and larger building blocks combine to form crystalline nanoporous materials with more surface area than zeolites. The Zeotype architecture of MIL-101 displays mesoporous cages with diameters of 29 Å (green) and 34 Å (red), featuring 12 Å pentagonal and 15 Å hexagonal openings. Credits: Science

Porous materials with large, regular, accessible cages and tunnels are increasingly in demand for many applications including chemical separation or purification, catalysis, molecular sensors, electronics and gas storage. Depending on their structure and pore size, these materials allow molecules of only certain shapes and sizes to enter the pores, a property known as shape selectivity. The environment within the pores can be very different to that outside, thus promoting chemical reactions that do not occur in the bulk material. Another prospective use is as templates for forming calibrated, monodisperse nanomaterials. In this respect, the larger the pores, the wider the range of reactants that can be manipulated or stored.

Férey and co-workers’ strategy combined three main ideas. First, discrete multi-atom building units were designed and generated in solution (Fig. 1). Second, with the aim of producing a compound with large pores, the building units were combined to produce larger units. For MIL-101 the key building unit is a supercluster of four smaller clusters linked by difunctional organic components to make a large tetrahedral assembly. The third idea involves being sure of what you’ve actually made, i.e. how to determine the structure of the new material. It is well known that it becomes increasingly difficult to grow highly diffracting single crystals as structures grow larger. When single crystals are unavailable, powder diffraction can provide sufficient information for structure solution. Based on their understanding of the ways the building units might combine, possible structural models were predicted and assessed via a computational strategy that calculated their relative stability. Favourable solutions were then compared with the high quality powder diffraction data collected from MIL-101 at ESRF. Once a good match between the predicted and measured powder patterns was seen, the researchers could be sure of the nature of their new material.

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Last Updated ( Oct 01, 2005 at 10:32 AM )
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The remainder of paradise - How important are whales and seals for polar ecosystems? PDF Print
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Everything Biology
Written by Everything Science   
Sep 17, 2005 at 11:00 PM
Polar regions are among the most inhospitable on earth; however, they harbour the largest animals , albeit in the ocean. Until recently, a seemingly endless food supply in the Arctic and Antarctic appeared to explain the large stocks of whales and seals. Now there is increasing evidence that the large mammals may have survived as a consequence of the polar regions’ harshness and inaccessibility to humans, and that their distribution may have been much wider in the past. Furthermore, it is not unlikely that the disappearance of large marine mammals from temperate oceans resulted in profound changes to the whole ecosystem.

humpbacks
Beneficiary or preserver: Humpback whales in polar waters. - Foto: Alfred-Wegener-Institut.

According to Professor Dr Victor Smetacek of the Alfred Wegener Institute for Polar and Marine Research and Dr Stephen Nicol from the University of Tasmania in Hobart, Australia, the ability to predict changes in polar ecosystems within the context of global climate change requires a better understanding of the ecological role of whales and seals. In their contribution now published in the scientific journal Nature, the two researchers present the hypothesis that large marine mammals have a central and stabilising role in marine ecosystems and were once widely distributed across all oceans.

In analogy to the large fish stocks in African lakes being dependent on hippos, large mammals may also control their environment in the coldest oceans on earth. It is already clear that the notion of short food chains with few organisms represents an oversimplified view of polar ecosystems. in the productivity of the Arctic and Antarctic is comparable to temperate oceans. However, large differences exist between the Arctic and Antarctic with regard to nutrient availability and key species in the food chain. In the Antarctic, availability of iron is the primary growth-limiting factor in the system.

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Last Updated ( Sep 18, 2005 at 05:43 PM )
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Black hole in search of a home PDF Print
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Everything Space
Written by Everything Science   
Sep 17, 2005 at 11:00 PM

The detection of a super massive black hole without a massive host galaxy is the surprising result from a large Hubble and VLT study of quasars. This is the first convincing discovery of such an object. One intriguing explanation is that the host galaxy may be made almost exclusively of dark matter.

No-host quasar compared with a normal quasar This figure shows two Hubble images of quasars from a sample of 20 relatively nearby quasars examined by a team of European astronomers two of the most powerful astronomical facilities available, the NASA/ESA Hubble Space Telescope and the ESO Very Large Telescope (VLT) at Cerro Paranal. The team confidently concludes that the quasar on the left, HE0450-2958 (in the centre, distance about 5 billion light-years) does not have a massive host galaxy. The quasar HE1239-2426 to the right (at a distance of 1.5 million light-years), has a normal host galaxy which displays large spiral arms. Although HE1239-2426 is much closer than HE0450-2958, the host galaxy of the latter would still be perfectly visible if it was as bright as the one of HE1239-2426. The lack of a prominent host galaxy around a very bright quasar (HE0450-2958) suggests a rare case of a collision between a seemingly normal spiral galaxy and an exotic object harbouring a very massive black hole. Also seen in the image to the left (above the quasar) is a strongly disturbed galaxy, showing all the signs of a recent collision. The VLT observations show it to be forming stars at a frantic rate. Below the quasar a foreground star is seen. The two images have been scaled to exhibit the same linear scale. The images were taken with the Advanced Camera for Surveys onboard the NASA/ESA Hubble Space Telescope. Image credit: NASA/ESA, ESO, Frédéric Courbin (Ecole Polytechnique Federale de Lausanne, Switzerland) & Pierre Magain (Universite de Liege, Belgium)

A team of European astronomers has used two of the most powerful astronomical facilities available, the NASA/ESA Hubble Space Telescope and the ESO Very Large Telescope (VLT) at Cerro Paranal, to confidently claim the discovery of a bright quasar without a massive host galaxy. Quasars are powerful and typically very distant source of prodigious amounts of radiation. They are commonly associated with galaxies containing an active central black hole.

The team conducted a detailed study of 20 relatively nearby quasars. For 19 of them, they found, as expected, that these super massive black holes are surrounded by a host galaxy. But when they studied the bright quasar HE0450-2958, located some 5 billion light-years away, they could not find evidence for a host galaxy. This, the astronomers suggest, may indicate a rare case of a collision between a seemingly normal spiral galaxy and an exotic object harbouring a very massive black hole.

With masses up to hundreds of millions that of the Sun, super massive black holes are commonly found in the centres of the most massive galaxies, including our own Milky Way. These black holes sometimes dramatically manifest themselves by devouring matter that they gravitationally swallow from their surroundings. The best fed of these shine as quasars (the name quasar is a contraction of quasi-stellar object, as they had initially been confused with stars).

The past decade of observations, largely with the Hubble telescope, has shown that quasars are normally associated with massive host galaxies. However, observing the host galaxy of a quasar is challenging work because the quasar completely outshines the host and masks the galaxy’s underlying structure.

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Last Updated ( Sep 18, 2005 at 06:01 PM )
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Nicaragua's Beaches Draw Hundreds of Thousands of Sea Turtles PDF Print
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Everything Biology
Written by Everything Science   
Sep 14, 2005 at 11:00 PM
MANAGUA, Nicaragua--(BUSINESS WIRE)--Sept. 14, 2005--Each year between July and December, hundreds of thousands of rare sea turtles visit Nicaragua to lay millions of eggs along the country's coasts. Nicaragua, a country abundant in nature and adventure, is one of only four countries believed to experience turtle hatchings of such large proportions.

GED_Turtles_ahsore
Two Olive Ridley turtles come ashore on the beaches of La Flor Wildlife Reserve in Nicaragua to nest. Photo courtesy of Terra Incognita Ecotours.

Nicaragua's majestic turtle migrations occur in waves referred to as "arribadas", or arrivals in Spanish. There is usually one "arribada" per month, but the exact date is influenced by a variety of factors, including the weather and moon. During each migration, several thousand turtles come ashore almost simultaneously and lay more than 100 ping-pong ball-sized eggs each. Remarkably, the turtles return to the exact same beach on which they were born, a phenomenon yet to be understood by scientists.

Both of Nicaragua's coasts are popular sites for nesting turtles. The country's less-developed Caribbean coast, specifically the Pearl Cays, is the nesting area of choice for thousands of rare Hawksbill, Green, Loggerhead, and Leatherback turtles. The warm water, inviting grass beds, and protective mangroves of these remote, white-sand beaches are also home to what is believed to be the world's largest remaining population of Green Sea Turtles. While visitors can only arrive via water or air, local charter operations such as La Costena, http://www.tacaregional.com/costena, and Atlantica Airlines provide flights to the region for less than $100.00 roundtrip.

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Last Updated ( Sep 15, 2005 at 07:28 PM )
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PollXT
How do you feel about Iceland opening commercial whaling?
Recently, Iceland has announced that it will allow the harvest of 9 fin whales, and 30 minke whales each year.
How do you feel about Iceland opening commercial whaling?
  This is the beginning of the end of whaling ban treaties.
  It's sad that the fin whales will probably go extinct because of this commercialization.
  I'm glad I live in a country where I don't have to worry about whaling.
  It doesn't matter. The whales will go extinct anyway due to other environmental factors.
  The whales will be fine. Iceland will not over-hunt.
  Who cares about the whales? What good are they swimming around in the ocean, anyway?
  
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